Analysis & Monitoring

Process Analysis Instruments & Online Analysers

Online and in-line analysers for water chemistry, gas composition and moisture - built for continuous duty in the process, not the laboratory.

What this category covers

A process analyser answers a chemistry question continuously, in the plant, without a sample being carried to a bench. pH, conductivity, dissolved oxygen, turbidity, residual chlorine, moisture and gas composition are all measured this way, and the result normally feeds a control loop, a dosing pump or a compliance record rather than a person.

What separates this category from laboratory analysis is the duty rather than the chemistry. An online analyser has to survive the sample as it actually arrives - hot, pressurised, carrying solids, gas slugs or fouling - and it is judged on drift and on the interval between services more than on the finest resolution it can display. A bench instrument measuring the same parameter can assume a clean, conditioned sample. An in-line instrument cannot.

Buyers arrive with a measurement point rather than a model: a tapping on a pipe, a tank, a basin or a stack. Most of the engineering that follows concerns the sample itself, because an analyser starved of a representative sample will report the wrong number reliably and consistently.

Product types in process analysis

Product typeHow it measuresUsually specified for
pH analyser Potential developed across a measuring and reference electrode pair, referred to a buffer calibrationEffluent neutralisation, chemical dosing and cooling water - any point where a control band is set around neutrality and the reference junction is the part that needs attention
ORP analyser Potential on an inert electrode read against a reference, following the oxidant rather than the acidDisinfection control, cyanide and chrome destruction, where the value tracks oxidising strength rather than pH
Conductivity analyser Resistance across a cell of known geometry, corrected to a reference temperatureDemineraliser and reverse-osmosis monitoring, rinse water, concentration control and leak detection between two media
Dissolved oxygen analyser Reduction current at a membrane-covered cell, or quenching of a luminescent spotAeration basin control, boiler feedwater and deaerator monitoring, and any dissolved-oxygen limit
Turbidity analyser Light scattered at an angle by suspended particles, or the loss of transmitted lightFilter performance, final effluent, raw water intake and drinking-water treatment
Chlorine analyser Colorimetric reaction with a reagent, or a membrane-covered amperometric cellDisinfection control downstream of chlorination or dosing, potable water and process wash circuits
Moisture analyser Capacitive, dewpoint or zirconia behaviour, with the sample conditioned upstreamCompressed air and instrument air, dryers and gas lines where condensation would damage what follows
Gas analyser Non-dispersive infrared absorption, electrochemical cell, paramagnetic or zirconia measurementCombustion trim, stack monitoring, process gas purity and biogas

TDS and salinity meters, water quality analysers, oxygen and CO2 analysers and the sample conditioning accessories that sit in front of an analyser are listed under this category as well.

How to choose a process analyser

There is rarely a single correct instrument for a duty, but there is always a shortlist that can be justified and a set of answers that eliminates the rest. These are the questions that decide it.

  • Sample condition before anything else: temperature, pressure, solids, oil, entrained gas, and whether the flow arrives as a steady stream or as a slug. Most analyser problems begin upstream of the analyser.
  • Whether the reading drives a control loop or a compliance record. A loop tolerates an occasional excursion that a discharge record does not, and the two duties justify different service intervals and different recording.
  • Span set around the control band rather than the widest range the instrument can display, because resolution spent outside the working band is resolution lost inside it.
  • Drift and calibration interval, which for an online instrument matter more than resolution - unattended operation is the entire point of being online.
  • Consumables and their availability: electrodes, membranes, electrolyte and reagent have finite lives, and whether they can be replaced without breaking the process connection sets the real operating cost.
  • Mounting and access: immersion, flow-through, bypass or retractable. A sensor that can be withdrawn without draining a line is worth having from the start rather than retrofitting later.
  • Sample conditioning: cooling, pressure reduction, filtration, degassing or a bypass with a flow indicator. Each one adds a failure point and belongs in the scope, not in a later conversation.
  • Output and integration: one isolated current loop per parameter, a digital link, alarm and wash relays, and whether a controller or a transmitter terminates the signal.
  • Environment at the enclosure: ambient temperature, humidity, corrosive atmosphere, washdown and area classification. The electronics housing often fails before the sensor does.

Working through the selection in order

  1. Name the measurement point and what the number is used for: control, alarm, dosing or a discharge record.
  2. Describe the sample as it leaves the tapping - temperature, pressure, solids, oil, gas, expected chemistry - and whether it is continuous or intermittent.
  3. Decide what the installation is allowed to change about the sample, and place the conditioning system in the scope at the same time as the analyser.
  4. Fix the span around the control band, note the resolution needed at the decision point, and record the calibration routine the reading has to support.
  5. Choose the sensing technology from the sample chemistry using the comparison above, then confirm the maintenance routine that technology implies.
  6. Choose the mounting from access and from whether the line can be isolated: immersion, in-line, bypass or retractable.
  7. Fix the outputs, the alarm and wash relays, and whether a local controller is required or the value goes directly to the control system.
  8. Decide the enclosure, the area classification and the wash arrangement, then confirm that service can be carried out safely and without a shutdown.

Comparing the technologies

TechnologyBest suited toLimitsTypical measurement
Glass electrode (potentiometric) General aqueous measurement with the widest body of operating experienceThe reference junction fouls, dries out or becomes poisoned; a two-buffer calibration is needed rather than a single-point checkpH, ORP
ISFET solid-state electrode Harsh or frequently cleaned service where a glass bulb would breakSensitive to light and to running dry, and the maintenance routine differs from glass, so the two are not interchangeable in a procedurepH
Amperometric membrane cell Continuous dissolved oxygen and residual chlorineMembrane and electrolyte are consumables; the flow past the membrane has to be stable or the reading drifts with itDissolved oxygen, chlorine
Optical scattering Turbidity and suspended solids from low to high levelReads the condition of the window as much as the water, so it depends on a clean and representative bypassTurbidity, suspended solids
Colorimetric Parameters that need a specific reagent reaction to become visibleReagent consumption and shelf life; dosing lines have to be kept clear, and the interval between services is set by reagent volumeChlorine and other colour-forming parameters
NDIR, zirconia and capacitive Gas composition, combustion oxygen and dewpointDust, condensate and aggressive components attack the cell unless they are conditioned out upstream firstCO2, CO, O2, moisture

Parameters to confirm before ordering

What is left after the technology is chosen is a list of values that only the installation can supply. These are the ones that change the model, the price or the lead time:

  • The measurement point: what is being measured, where it sits in the process, and what the reading controls.
  • Sample conditions at the tapping: temperature, pressure, flow, solids, oil and grease, entrained gas and any intermittent behaviour.
  • Chemistry that affects the sensor: expected range, concentration, and any species that would foul or poison it.
  • The span and the control band, with the resolution needed at the point where the decision is made.
  • The maintenance routine expected: who calibrates, how often, and whether the sensor can be withdrawn without draining the line.
  • Sample conditioning required: cooling, pressure reduction, filtration, degassing, or a bypass with a flow indicator.
  • Mounting and connection: immersion, flow-through, retractable fitting or clamp-on, with the pipe or basin dimensions and material.
  • Outputs and communication: number of isolated current loops, digital link, relay alarms, and where the signal terminates.
  • Power supply and enclosure: supply voltage, panel or wall mounting, ingress protection and washdown arrangement.
  • Environment and classification: ambient conditions, corrosive atmosphere, and whether the installation area is classified.

Figures are quoted, not assumed

Specifications vary by model and application, so no performance figure is stated on this page. Where a parameter has not been documented for a particular model, the product page says so rather than filling the gap with a plausible number. Send the values above and we will return the ones the selected model actually holds.

Where these instruments are used

Frequently asked

Process Analysis buying questions

The questions that come up before an order rather than after it. If yours is not here, send it with the requirement and we will answer it in the quotation.

What is the difference between an online analyser and a laboratory instrument measuring the same parameter?

The duty, not the chemistry. An online analyser works on the sample as the process delivers it and is expected to run unattended, so its conditioning, its drift and its service interval are the deciding characteristics. A laboratory instrument works on a clean, prepared sample and is judged on resolution. The same parameter can therefore be specified two completely different ways, and it is worth stating at the enquiry which of the two the application actually needs.

Do I need a sample conditioning system as well as the analyser?

Usually, and it should be quoted together with the analyser rather than after it. A sample outside the sensor limits - too hot, too high a pressure, carrying solids or gas slugs - will read incorrectly regardless of how good the analyser is. Send the conditions at the tapping point and we will say what has to sit between the tapping and the sensor.

How often does an online analyser need calibrating?

It depends on the chemistry and on the service, and a clean water point is not comparable with a fouling effluent line, so the interval is set by experience on that point rather than by a general rule. What can be quoted is the routine the instrument supports: one-point or two-point calibration, automatic wash, and whether the sensor can be withdrawn while the process runs.

Can one analyser measure more than one parameter?

Multi-parameter transmitters are common for the water chemistry group, where pH, ORP, conductivity, dissolved oxygen and turbidity share a controller and a set of outputs. Gas and moisture measurement is normally a separate instrument. Where one unit covers several parameters, confirm that each sensor can still be replaced and calibrated on its own.

What output should a process analyser provide?

At minimum one isolated current loop per parameter and a relay for alarm or wash. Where the value is logged or reported for compliance, a digital link is worth having so that the recorded figure and the displayed figure are demonstrably the same one. State where the signal terminates and how many outputs are needed.

Is hazardous-area approval needed for a water analysis point?

Not for a typical effluent or potable water point, but it is needed wherever the atmosphere is classified - a dosing room handling a flammable reagent, for example, or a gas measurement inside a process area. State the classification of the installation including any zone around the tapping, and the enclosure and electronics will be quoted to match it.

Available now

Published products in Process Analysis

Illustrative reference plate for the Online pH Analyzer (PHA-300)

PHA-300 · pH Analyzers Reference listing

Online pH Analyzer

Continuous pH measurement with automatic temperature compensation, a differential or combined electrode and a 4-20 mA output for control or recording.

Measuring range
0 to 14 pH
Accuracy
±0.02 pH
Temperature compensation
Automatic, PT1000
Output
4-20 mA, RS485 Modbus

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